5. Bubble Point

The bubble-point temperature is the temperature of stage j at which the liquid mixture begins to boil.

Here, the pressure \(p\) and the mole fractions of the liquid, \(x_i\) will be known. We wish to find the temperature, \(T\), at which

\[\sum_i y_i = 1.0\]

The gas-phase mole fractions are calculated as

\[y_i = K_i(T) x_i\]

Where \(K_i\) comes from the equilibrium relationship that has been chosen.

The calculation results in finding the temperature that satisfies the stoichiometric equation

\[\sum_i y_i = \sum_i K_i (T) x_i = 1.0\]

The calculation is performed using the function below:

distillation.bubble_point.calculation.bubble_point(x, K, p, T_guess)[source]
Parameters
  • x – mole fractions in liquid

  • p – total pressure

  • K – functions calculating K for each component

  • T_guess – guess temperature

Returns

Temperature at which the liquid mixture begins to boil.